Catalytic Solvolytic and Hydrolytic Degradation of Toxic Methyl Paraoxon with La(catecholate)-Functionalized Porous Organic Polymers

نویسندگان

  • Ryan K. Totten
  • Mitchell H. Weston
  • Jin Kuen Park
  • Omar K. Farha
  • Joseph T. Hupp
  • SonBinh T. Nguyen
چکیده

Two robust catechol-functionalized porous organic polymers (catPOPs) with different Td-directing nodes were synthesized using a cobalt-catalyzed acetylene trimerization (CCAT) strategy. Postsynthesis metallation was readily carried out with La(acac)3 to afford catalytically active Lafunctionalized catPOPs for the solvolytic and hydrolytic degradation of the toxic organophosphate compound methyl paraoxon, a simulant for nerve agents.

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تاریخ انتشار 2013